Di-μ-oxido-bis­({(R)-(–)-2-[1-(2-amino­propyl­imino)eth­yl]-1-naphtholato-κ3 N,N′,O}oxidovanadium(V))

نویسندگان

  • Grzegorz Romanowski
  • Artur Sikorski
  • Andrzej Wojtczak
چکیده

In the title dinuclear compound, [V(2)(C(15)H(17)N(2)O)(2)O(4)], each V(V) atom is six-coordinated by one oxide group, and by two N and one O atom of the tridentate Schiff base ligand, and bridged by two additional oxide O atoms, resulting in a centrosymmetric dimer. The metal centre has a distorted octa-hedral coordination with the monoanionic Schiff base ligand occupying one equatorial and two axial coordination positions. The separation between V atoms is 3.214 (3) Å. In the crystal structure, there are N-H⋯O, C-H⋯O and C-H⋯π hydrogen bonds, and π-π inter-actions.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008